Issue 10, 2012
From the journal:

Chemical Communications

Shuffle off the classic β-Si elimination by Ni-NHC cooperation: implication for C–C forming reactions involving Ni-alkyl-β-silanes†‡

Chun-Yu Ho*a  and  Lisi Hea  

* Corresponding authors

a Center of Novel Functional Molecules, Department of Chemistry, The Chinese University of Hong Kong, and CUHK SZRI
E-mail: jasonhcy@cuhk.edu.hk

Abstract

Via a cooperation of NHC, Si substituents and a M center, β-Si elimination was attenuated, revealing a new way to attain a high Ni-β-SiR3 : Ni-σ-SiR3 ratio. The scope is illustrated by a head-to-tail vinylsilane-α-olefin hydroalkenylation.

Graphical abstract: Shuffle off the classic β-Si elimination by Ni-NHC cooperation: implication for C–C forming reactions involving Ni-alkyl-β-silanes

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Article information

DOI
https://doi.org/10.1039/C1CC14593B
Article type
Communication
Submitted
27 Jul 2011
Accepted
07 Nov 2011
First published
25 Nov 2011

Chem. Commun., 2012,48, 1481-1483

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Shuffle off the classic β-Si elimination by Ni-NHC cooperation: implication for C–C forming reactions involving Ni-alkyl-β-silanes

C. Ho and L. He, Chem. Commun., 2012, 48, 1481 DOI: 10.1039/C1CC14593B

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