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The Ru/ZnO–ZrOx(OH)y catalyst is very efficient for the selective hydrogenation of benzene to cyclohexene, and the yield of cyclohexene can reach 56% without using any additive. This work provides a highly efficient, cheap and clean method to produce cyclohexene.

Graphical abstract: Highly selective benzene hydrogenation to cyclohexene over supported Ru catalyst without additives

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