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Dehydrogenation of Me2NH·BH3 (1) by group 4 metallocene alkyne complexes of the type Cp2M(L)(η2-Me3SiC2SiMe3) [Cp = η5-cyclopentadienyl; M = Ti, no L (2Ti); M = Zr, L = pyridine (2Zr)] and group 4 metal amido complexes of the type M(NMe2)4 [M = Ti (8Ti), Zr (8Zr)] is presented.

Graphical abstract: Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds

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