Issue 17, 2011
From the journal:

CrystEngComm

Pseudopolymorphism of an adamantane-based bisphenol containing water molecules: a role of clathrate hydrates in hydrogen-bonded networks†

Masahide Tominaga,*a   Hyuma Masu‡a  and  Isao Azumaya*a  

* Corresponding authors

a Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, 1314-1 Shido, Sanuki, Kagawa, Japan
E-mail: tominagam@kph.bunri-u.ac.jp, azumayai@kph.bunri-u.ac.jp
Fax: +81 87 894 0181
Tel: +81 87 894 5111 x 6305

Abstract

An adamantane-based bisphenol (1) assembled into three types of 2D layers with or without channels or a doubly interpenetrated 3D network bearing clathrate hydratesviahydrogen bonds. The different stoichiometries of 1 and water facilitated the formation of the diverse molecular packing structures. Infinite chains and finite triangle clusters of water were formed within the channels and cavities.

Graphical abstract: Pseudopolymorphism of an adamantane-based bisphenol containing water molecules: a role of clathrate hydrates in hydrogen-bonded networks

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Article information

DOI
https://doi.org/10.1039/C1CE05253E
Article type
Communication
Submitted
25 Feb 2011
Accepted
29 Jun 2011
First published
13 Jul 2011

CrystEngComm, 2011,13, 5299-5302

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Pseudopolymorphism of an adamantane-based bisphenol containing water molecules: a role of clathrate hydrates in hydrogen-bonded networks

M. Tominaga, H. Masu and I. Azumaya, CrystEngComm, 2011, 13, 5299 DOI: 10.1039/C1CE05253E

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