Issue 19, 2011
From the journal:

CrystEngComm

A disulfideligand with axial chirality generated in situ for the construction of an unusual hxg topological coordination polymer†

Ning Yuan,ab   Tianlu Sheng,a   Jian Zhang,a   Chongbin Tian,a   Shengmin Hu,a   Xihe Huang,c   Fei Wanga  and  Xintao Wu*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, PR China

b Graduate University of Chinese Academy of Sciences, Beijing, PR China

c State Key Laboratory Breeding Base of Photocatalysis, Department of Chemistry, Fuzhou University, Fuzhou, PR China

Abstract

A novel coordination polymer [NaMn2(dmdn)3(H2O)6]·4.5H2O (dmdn = 6,6′-dimercaptodinicotinate) (1) was prepared and characterized by single-crystal X-ray diffraction along with powder XRD, IR, elemental analyses and magnetic analyses. Compound 1, featuring a rarely reported 2-fold interpenetrated (46,69)-hxg network based on the wheel-like clusters ligated by the in situ generated dmdn ligands as the six-connected approximately planar nodes, was obtained by slow evaporation of mna (mna =6-mercaptonicotinic acid) and NaOH with MnCl2·4H2O in distilled water at room temperature. In addition, the magnetic property of 1 has also been investigated in detail.

Graphical abstract: A disulfide ligand with axial chirality generated in situ for the construction of an unusual hxg topological coordination polymer

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Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CE05154G
Article type
Paper
Submitted
31 Jan 2011
Accepted
01 Jul 2011
First published
11 Aug 2011

CrystEngComm, 2011,13, 5951-5955

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A disulfide ligand with axial chirality generated in situ for the construction of an unusual hxg topological coordination polymer

N. Yuan, T. Sheng, J. Zhang, C. Tian, S. Hu, X. Huang, F. Wang and X. Wu, CrystEngComm, 2011, 13, 5951 DOI: 10.1039/C1CE05154G

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