Issue 37, 2011

De novo synthesis of deoxy sugarvia a Wharton rearrangement

Abstract

A highly divergent synthesis of α-fuco-, α-6-deoxy-allo-, α-6-deoxy-altro-pyranosides has been achieved. This route utilizes a Wharton rearrangement as part of a new post-glycosylation transformation strategy.

Graphical abstract: De novo synthesis of deoxy sugarvia a Wharton rearrangement

Supplementary files

Article information

Article type
Communication
Submitted
27 Jun 2011
Accepted
18 Jul 2011
First published
18 Aug 2011

Chem. Commun., 2011,47, 10251-10253

De novo synthesis of deoxy sugarvia a Wharton rearrangement

H. L. Wang and G. A. O'Doherty, Chem. Commun., 2011, 47, 10251 DOI: 10.1039/C1CC13837E

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