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Two ruthenium aqua complexes were shown to be effective catalysts in chemical and photochemical oxidation of hydrocarbons. A remarkable activity (up to 90% yield and 100% selectivity) was performed in conversion of sulfide to sulfoxide by homogeneous photooxidation.

Graphical abstract: Chemical and photochemical oxidation of organic substrates by ruthenium aqua complexes with water as an oxygen source

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