Issue 11, 2011
From the journal:

Chemical Communications

Copper-catalyzed synthesis of alkynylphosphine derivatives: unprecedented use of nucleophilic phosphorus compounds†

Elise Bernoud,a   Carole Alayrac,a   Olivier Delacroixa  and  Annie-Claude Gaumont*a  

* Corresponding authors

a Laboratoire de Chimie Moléculaire et Thio-organique, UMR CNRS 6507, INC3M, FR 3038, ENSICAEN & Université de Caen, 6 boulevard du Maréchal Juin, 14050 Caen, France
E-mail: annie-claude.gaumont@ensicaen.fr
Fax: +33 231 45 28 77
Tel: +33 231 45 28 73

Abstract

A new and smooth approach towards alkynylphosphine derivatives is described. It relies on the unprecedented catalytic coupling of secondary phosphine boranes with alkynyl bromides using the CuI/1,10-phenanthroline couple.

Graphical abstract: Copper-catalyzed synthesis of alkynylphosphine derivatives: unprecedented use of nucleophilic phosphorus compounds

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Article information

DOI
https://doi.org/10.1039/C0CC04645K
Article type
Communication
Submitted
27 Oct 2010
Accepted
10 Jan 2011
First published
25 Jan 2011

Chem. Commun., 2011,47, 3239-3241

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Copper-catalyzed synthesis of alkynylphosphine derivatives: unprecedented use of nucleophilic phosphorus compounds

E. Bernoud, C. Alayrac, O. Delacroix and A. Gaumont, Chem. Commun., 2011, 47, 3239 DOI: 10.1039/C0CC04645K

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