Unexpected pincer-type coordination (κ3-SBS) within a zerovalent platinum metallaboratrane complex

Gareth R. Owen; P. Hugh Gould; Alex Hamilton; Nikolaos Tsoureas

doi:10.1039/B917733G

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Unexpected pincer-type coordination (κ³-SBS) within a zerovalent platinum metallaboratrane complex†

Gareth R. Owen,‡*^a P. Hugh Gould,^a Alex Hamilton^a and Nikolaos Tsoureas^a

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^a The School of Chemistry, University of Bristol, Bristol, UK
E-mail: gareth.owen@bristol.ac.uk
Fax: 0117 925 1295
Tel: 0117 928 7652

Abstract

The first structurally characterised zerovalent platinum complex to contain a tridentate pincer-type coordination mode (κ³-SBS) is presented, raising further questions concerning the geometries and trans influence of Z-type ligands.

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Article information

DOI: https://doi.org/10.1039/B917733G
Article type: Communication
Submitted: 01 Jul 2009
Accepted: 08 Sep 2009
First published: 16 Sep 2009

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Dalton Trans., 2010,39, 49-52

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Unexpected pincer-type coordination (κ³-SBS) within a zerovalent platinum metallaboratrane complex

G. R. Owen, P. H. Gould, A. Hamilton and N. Tsoureas, Dalton Trans., 2010, 39, 49 DOI: 10.1039/B917733G

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Dalton Transactions