Issue 39, 2010
From the journal:

Chemical Communications

A photoreactive crystalline quasiracemate†

Rebecca C. Grove,a   Steven H. Malehorn,a   Meghan E. Breena  and  Kraig A. Wheeler*a  

* Corresponding authors

a Department of Chemistry, Eastern Illinois University, Charleston, Illinois, USA
E-mail: kawheeler@eiu.edu
Fax: +1 217 581 6613
Tel: +1 217 581 3119

Abstract

Rationally designed racemic and quasiracemic sulfonamidecinnamic acids assemble to give hydrogen-bonded dimers with coplanar alignment of neighboring olefins. The quasiracemate phase contains near inversion-related motifs with chemically distinct components forming supramolecular heterodimers that undergo asymmetric photodimerization.

Graphical abstract: A photoreactive crystalline quasiracemate

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Article information

DOI
https://doi.org/10.1039/C0CC02775H
Article type
Communication
Submitted
24 Jul 2010
Accepted
24 Aug 2010
First published
13 Sep 2010

Chem. Commun., 2010,46, 7322-7324

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A photoreactive crystalline quasiracemate

R. C. Grove, S. H. Malehorn, M. E. Breen and K. A. Wheeler, Chem. Commun., 2010, 46, 7322 DOI: 10.1039/C0CC02775H

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