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Abstract | Cited by

Construction of formally antiaromatic discotic twins based on dehydroannulene cores linked through non-adjacent positions on triphenylenes gives stable molecules with intriguing molecular and supramolecular properties and, unlike the majority of discotic triphenylenes and similar materials, the twins form nematic mesophases on heating.

Graphical abstract: Antiaromatic twinned triphenylene discotics showing nematic phases and 2-dimensional π-overlap in the solid state

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