Issue 5, 2009
From the journal:

Organic & Biomolecular Chemistry

Palladium-catalyzed decarboxylative cross-coupling reaction of cinnamic acid with aryl iodide†

Zhiyong Wang,a   Qiuping Ding,a   Xiaodan Hea  and  Jie Wu*ab  

* Corresponding authors

a Department of Chemistry, Fudan University, 220 Handan Road, Shanghai, China
E-mail: jie_wu@fudan.edu.cn
Fax: +86 21 6510 2412
Tel: +86 21 5566 4619

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai, China

Abstract

A highly effective decarboxylative cross-coupling reaction of cinnamic acid with aryl iodide catalyzed by the combination of palladium chloride and CyJohnPhos in the presence of Ag2CO3 as an additive is described. The desired carbon-carbon bond formation proceeds efficiently with good functional-group tolerance.

Graphical abstract: Palladium-catalyzed decarboxylative cross-coupling reaction of cinnamic acid with aryl iodide

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Article information

DOI
https://doi.org/10.1039/B821870F
Article type
Communication
Submitted
05 Dec 2008
Accepted
05 Jan 2009
First published
14 Jan 2009

Org. Biomol. Chem., 2009,7, 863-865

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Palladium-catalyzed decarboxylative cross-coupling reaction of cinnamic acid with aryl iodide

Z. Wang, Q. Ding, X. He and J. Wu, Org. Biomol. Chem., 2009, 7, 863 DOI: 10.1039/B821870F

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