Issue 37, 2009
From the journal:

Dalton Transactions

First reductive dimerization of a polycyclic azine†

Jean-Claude Berthet,*a   Pierre Thuéry,a   Cécile Baudin,b   Bruno Boizotb  and  Michel Ephritikhine*a  

* Corresponding authors

a CEA, IRAMIS, SIS2M, CNRS URA 331, France
E-mail: jean-claude.berthet@cea.fr, michel.ephritikhine@cea.fr
Fax: +33 169 08 66 40
Tel: +33 169 08 60 42

b CEA, IRAMIS, LSI, Ecole Polytechnique, Aile 5, Route de Saclay, France

Abstract

The tptz molecule is reduced by potassium into its anion-radical in the compound K(tptz)2 (1), whereas it is reductively coupled by SmI2 and UI3(py)4 into the bis-triazinide ligand in the dinuclear complexes [Sm2(tptz–tptz)(DMF)8][I]4·3.5DMF (2·3.5DMF) and U2I6(tptz–tptz)(MeCN)2·2MeCN (3·2MeCN) where each metal ion occupies a pentadentate N5 cavity of the [tptz–tptz]2– ligand.

Graphical abstract: First reductive dimerization of a polycyclic azine

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Article information

DOI
https://doi.org/10.1039/B909547K
Article type
Communication
Submitted
01 Apr 2009
Accepted
20 Jul 2009
First published
31 Jul 2009

Dalton Trans., 2009, 7613-7616

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First reductive dimerization of a polycyclic azine

J. Berthet, P. Thuéry, C. Baudin, B. Boizot and M. Ephritikhine, Dalton Trans., 2009, 7613 DOI: 10.1039/B909547K

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