Issue 25, 2009
From the journal:

Dalton Transactions

Mixed-valent manganese phosphonate clusters prepared under microwave-assisted and ambient conditions†

Jin-Tang Li,a   Yun-Sheng Ma,a   Shao-Gang Li,a   Deng-Ke Cao,a   Yi-Zhi Li,a   You Songa  and  Li-Min Zheng*a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P. R. China
E-mail: lmzheng@nju.edu.cn
Fax: +86-25-83314502

Abstract

Mixed-valent manganese phosphonate clusters [MnII8MnIII2O2(O3PC10H7)4(C6H5CO2)10(py)4(H2O)2] (1) and [MnII4MnIII9O4(OH)2(O3PC10H7)10(C6H5CO2)5(py)8(H2O)6] (2) are reported. Compound 1 is the first example of manganese phosphonate clusters prepared through a microwave-assisted technique. While compound 2 is obtained under ambient condition, and exhibits slow magnetic relaxation behaviour at low temperature.

Graphical abstract: Mixed-valent manganese phosphonate clusters prepared under microwave-assisted and ambient conditions

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Article information

DOI
https://doi.org/10.1039/B901121H
Article type
Paper
Submitted
19 Jan 2009
Accepted
17 Apr 2009
First published
28 May 2009

Dalton Trans., 2009, 5029-5034

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Mixed-valent manganese phosphonate clusters prepared under microwave-assisted and ambient conditions

J. Li, Y. Ma, S. Li, D. Cao, Y. Li, Y. Song and L. Zheng, Dalton Trans., 2009, 5029 DOI: 10.1039/B901121H

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