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Abstract | Cited by

Co-sublimation of the two dithiadiazolyl radicals [PhCNSSN]2 (1)2 and [C6F5CNSSN]2 (2)2 yielded the mixed π*–π* dimer [PhCNSSN][C6F5CNSSN] (3) exhibiting aryl–perfluoroaryl π–π interactions.

Graphical abstract: Co-crystallisation of thiazyl radicals: preparation and crystal structure of [PhCNSSN][C6F5CNSSN]

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