Issue 32, 2009

A catalytic synthesis of selectively substituted biaryls through sequential intermolecular coupling involving arene and ketone C–H bond functionalization

Abstract

Selectively substituted biaryls containing a ketone unit are obtained under mild conditions in satisfactory yields by a simple reaction of ortho-substituted aryl iodides and ketones in the presence of palladium and norbornene as catalysts.

Graphical abstract: A catalytic synthesis of selectively substituted biaryls through sequential intermolecular coupling involving arene and ketone C–H bond functionalization

Supplementary files

Article information

Article type
Communication
Submitted
08 May 2009
Accepted
12 Jun 2009
First published
01 Jul 2009

Chem. Commun., 2009, 4892-4894

A catalytic synthesis of selectively substituted biaryls through sequential intermolecular coupling involving arene and ketone C–H bond functionalization

G. Maestri, N. Della Ca’ and M. Catellani, Chem. Commun., 2009, 4892 DOI: 10.1039/B909207B

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