Issue 42, 2008
From the journal:

Chemical Communications

Synthesis of poly(vinyl acetate) block copolymers by successive RAFT and ATRP with a bromoxanthate iniferter†

Renaud Nicolaÿ,a   Yungwan Kwaka  and  Krzysztof Matyjaszewski*a  

* Corresponding authors

a Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh PA 15213, USA
E-mail: km3b@andrew.cmu.edu
Fax: 1-412-268-6897
Tel: 1-412-268-3209

Abstract

Poly(vinyl acetate)-b-polystyrene, poly(vinyl acetate)-b-poly(methyl acrylate) and poly(vinyl acetate)-b-poly(methyl methacrylate) block copolymers with low polydispersity (Mw/Mn < 1.25) were prepared by successive reversible addition–fragmentation chain transfer (RAFT) polymerization and atom transfer radical polymerization (ATRP) employing a bromoxanthateiniferter (initiator-transfer agent-terminator).

Graphical abstract: Synthesis of poly(vinyl acetate) block copolymers by successive RAFT and ATRP with a bromoxanthate iniferter

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Article information

DOI
https://doi.org/10.1039/B810778E
Article type
Communication
Submitted
25 Jun 2008
Accepted
21 Jul 2008
First published
18 Sep 2008

Chem. Commun., 2008, 5336-5338

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Synthesis of poly(vinyl acetate) block copolymers by successive RAFT and ATRP with a bromoxanthate iniferter

R. Nicolaÿ, Y. Kwak and K. Matyjaszewski, Chem. Commun., 2008, 5336 DOI: 10.1039/B810778E

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