Issue 19, 2008
From the journal:

Chemical Communications

The 8 : 1 : 1 ternary hybrid framework in the system [EDT-TTF˙+][1,4-bis(iodoethynyl)benzene][Re6Se8(CN)6]4−: dual noncovalent expression of the octahedral halogen-bond hexa-acceptor nanonode†

Anne-Lise Barrès,a   Abdelkrim El-Ghayoury,a   Leokadiya V. Zorina,a   Enric Canadell,b   Pascale Auban-Senzierc  and  Patrick Batail*a  

* Corresponding authors

a Laboratoire de Chimie, Ingénierie Moléculaire et Matériaux d’Angers, Université d’Angers, CNRS, 2 Boulevard Lavoisier, Angers, France
E-mail: patrick.batail@univ-angers.fr
Fax: +33 241 735 011

b Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus de la UAB, Bellaterra, Spain

c Laboratoire de Physique des Solides, Université de Paris-Sud, CNRS, Orsay, France

Abstract

Complementary shapes of the neutral symmetrical halogen-bond bis-donor core and octahedral inorganic cluster core prevent halogen-bonded polymers developing in more than one direction, favouring further templating by conducting radical cation slabs and yielding an 8 : 1 : 1 phase formulation instead of n : 2 : 1, with a 2D net, or m : 3 : 1, with a pseudo-cubic architecture, which may in principle also be targeted.

Graphical abstract: The 8 : 1 : 1 ternary hybrid framework in the system [EDT-TTF˙+][1,4-bis(iodoethynyl)benzene][Re6Se8(CN)6]4−: dual noncovalent expression of the octahedral halogen-bond hexa-acceptor nanonode

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Article information

DOI
https://doi.org/10.1039/B800571K
Article type
Communication
Submitted
14 Jan 2008
Accepted
31 Mar 2008
First published
08 Apr 2008

Chem. Commun., 2008, 2194-2196

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The 8 : 1 : 1 ternary hybrid framework in the system [EDT-TTF˙+][1,4-bis(iodoethynyl)benzene][Re6Se8(CN)6]4−: dual noncovalent expression of the octahedral halogen-bond hexa-acceptor nanonode

A. Barrès, A. El-Ghayoury, L. V. Zorina, E. Canadell, P. Auban-Senzier and P. Batail, Chem. Commun., 2008, 2194 DOI: 10.1039/B800571K

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