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Two water-soluble tris(2-aminoethylamine) (tren) capped iron porphyrins were synthesized. The stability of their dioxygen adducts was studied in phosphate buffer, leading to half-life times around 7 min for the oxygenated species.

Graphical abstract: Dioxygen binding of water-soluble iron(ii) porphyrins in phosphate buffer at room temperature

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