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Abstract | Cited by

We report the first catalytic Sakurai reaction of N-alkoxycarbonylamino sulfones with allylsilanes. The allylation reaction of N-alkoxycarbonylamino phenylsulfones with allyltrimethylsilane proceeded smoothly with low catalyst loading of bismuth triflate (2.0 mol%) to afford the corresponding protected homoallylic amines in moderate to very good yields (up to 96%).

Graphical abstract: The first catalytic Sakurai reaction of N-alkoxycarbonylamino sulfones with allyltrimethylsilane

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