Issue 10, 2006
From the journal:

Green Chemistry

Alternating CO/tert-butylstyrene copolymerisation using soluble cationic palladium complexes in supercritical carbon dioxide†

Marta Giménez-Pedrós,a   Clara Tortosa-Estorach,a   Amaia Bastero,a   Anna M. Masdeu-Bultó,*a   Maurizio Solinasb  and  Walter Leitner*b  

* Corresponding authors

a Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, c/Marcel·lí Domingo, s/n, Tarragona, Spain
E-mail: annamaria.masdeu@urv.net
Fax: +34 977559563
Tel: +34 977558779

b Institut für Technische und Makromolekulare Chemie, Worringerweg 1, Aachen, Germany
E-mail: leitner@itmc.rwth-aachen.de
Fax: +49-(0)241-80 221 77
Tel: + 49-(0)241-80 264 80

Abstract

Polyketones (Mw = 56 000–87 000 g mol−1) with very narrow molecular weight distributions have been obtained by CO/tert-butylstyrene copolymerisation in supercritical carbon dioxide using palladium complexes with perfluorinated bipyridine and phenanthroline ligands.

Graphical abstract: Alternating CO/tert-butylstyrene copolymerisation using soluble cationic palladium complexes in supercritical carbon dioxide

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Article information

DOI
https://doi.org/10.1039/B607610F
Article type
Communication
Submitted
30 May 2006
Accepted
27 Jul 2006
First published
07 Aug 2006

Green Chem., 2006,8, 875-877

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Alternating CO/tert-butylstyrene copolymerisation using soluble cationic palladium complexes in supercritical carbon dioxide

M. Giménez-Pedrós, C. Tortosa-Estorach, A. Bastero, A. M. Masdeu-Bultó, M. Solinas and W. Leitner, Green Chem., 2006, 8, 875 DOI: 10.1039/B607610F

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