Issue 44, 2006
From the journal:

Chemical Communications

Self-exchange electron transfer in high oxidation state non-oxo metal complexes: amavadin†

Jeremy Lenhardt,a   Bharat Baruah,b   Debbie C. Crans*b  and  Michael D. Johnson*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico, USA
E-mail: johnson@nmsu.edu
Fax: +1 505 646 2394
Tel: +1 505 646 3627

b Department of Chemistry, Colorado State University, Fort Collins, Colorado, USA
E-mail: crans@lamar.colostate.edu
Fax: +1 970 491 1801
Tel: +1 970 491 7635

Abstract

The electron transfer self-exchange rate constant between the oxidized and reduced forms of amavadin equals ∼1 × 105 dm3 mol−1 s−1 at 25 °C and represents the first unambiguous example for a vanadium(IV/V) couple.

Graphical abstract: Self-exchange electron transfer in high oxidation state non-oxo metal complexes: amavadin

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Article information

DOI
https://doi.org/10.1039/B610751F
Article type
Communication
Submitted
27 Jul 2006
Accepted
20 Sep 2006
First published
12 Oct 2006

Chem. Commun., 2006, 4641-4643

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Self-exchange electron transfer in high oxidation state non-oxo metal complexes: amavadin

J. Lenhardt, B. Baruah, D. C. Crans and M. D. Johnson, Chem. Commun., 2006, 4641 DOI: 10.1039/B610751F

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