Issue 47, 2006
From the journal:

Chemical Communications

Enhanced catalase-like activity of manganese salen complexes in water: effect of a three-dimensionally fixed auxiliary†

Yoritada Watanabe,a   Azusa Namba,a   Naoki Umezawa,a   Masatoshi Kawahata,b   Kentaro Yamaguchib  and  Tsunehiko Higuchi*a  

* Corresponding authors

a Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya, Japan
E-mail: higuchi@phar.nagoya-cu.ac.jp
Fax: +81-52-836-3435
Tel: +81-52-836-3435

b Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Shido Sanuki-city, Kagawa, Japan

Abstract

A new Mn(Salen) complex bearing an ureido group as an auxiliary that is three-dimensionally fixed by a cyclopentane ring fused to the Salen structure was developed. This compound exhibited considerably higher catalase-like activity than the original Mn(Salen), i.e., the cyclopentane-fused Mn(Salen) without the auxiliary, under near-physiological conditions.

Graphical abstract: Enhanced catalase-like activity of manganese salen complexes in water: effect of a three-dimensionally fixed auxiliary

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Article information

DOI
https://doi.org/10.1039/B608846E
Article type
Communication
Submitted
22 Jun 2006
Accepted
20 Sep 2006
First published
09 Oct 2006

Chem. Commun., 2006, 4958-4960

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Enhanced catalase-like activity of manganese salen complexes in water: effect of a three-dimensionally fixed auxiliary

Y. Watanabe, A. Namba, N. Umezawa, M. Kawahata, K. Yamaguchi and T. Higuchi, Chem. Commun., 2006, 4958 DOI: 10.1039/B608846E

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