Chiral polymers by iterative tandem catalysis†
Abstract
Racemic ω-substituted caprolactones can be completely converted into chiral polyesters of remarkable MW and high ee by combining lipase-catalyzed
* Corresponding authors
a
Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven, The Netherlands
E-mail:
e.w.meijer@tue.nl
Fax: +31 (0)40 2451036
Tel: +31 (0)40 2473101
b Process Development Group, Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven, The Netherlands
Racemic ω-substituted caprolactones can be completely converted into chiral polyesters of remarkable MW and high ee by combining lipase-catalyzed
J. van Buijtenen, B. A. C. van As, J. Meuldijk, A. R. A. Palmans, J. A. J. M. Vekemans, L. A. Hulshof and E. W. Meijer, Chem. Commun., 2006, 3169 DOI: 10.1039/B606241E
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