Enantiomerically pure 2-(aryloxymethyl)aziridines are efficiently transformed into chiral N-(2-bromo-3-aryloxypropyl)amines via a regio- and stereospecific ring opening of the intermediate aziridinium salts, and the experimental results are rationalized on the basis of some high level ab initio calculations.
M. D'hooghe, V. Van Speybroeck, M. Waroquier and N. De Kimpe, Chem. Commun., 2006, 1554 DOI: 10.1039/B518298K
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