Exploiting the palladium[0]-catalysed Ullmann cross-coupling reaction in natural products chemistry: application to a total synthesis of the alkaloid (±)-aspidospermidine

Martin G. Banwell; David W. Lupton

doi:10.1039/B415977B

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Exploiting the palladium[0]-catalysed Ullmann cross-coupling reaction in natural products chemistry: application to a total synthesis of the alkaloid (±)-aspidospermidine

Martin G. Banwell*^a and David W. Lupton^a

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^a Research School of Chemistry, Institute of Advanced Studies, The Australian National University, Canberra, Australia
E-mail: mgb@rsc.anu.edu.au

Abstract

Azide 14, available through the title cross-coupling process, has been converted, via the ring-fused aziridine 15, into the alkaloid aspidospermidine.

This article is part of the themed collection: Chemistry Nobel 2010 Web Collection: Cross-coupling reactions in organic chemistry

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DOI: https://doi.org/10.1039/B415977B
Article type: Communication
Submitted: 19 Oct 2004
Accepted: 15 Nov 2004
First published: 07 Dec 2004

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Org. Biomol. Chem., 2005,3, 213-215

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Exploiting the palladium[0]-catalysed Ullmann cross-coupling reaction in natural products chemistry: application to a total synthesis of the alkaloid (±)-aspidospermidine

M. G. Banwell and D. W. Lupton, Org. Biomol. Chem., 2005, 3, 213 DOI: 10.1039/B415977B

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Organic & Biomolecular Chemistry

Exploiting the palladium[0]-catalysed Ullmann cross-coupling reaction in natural products chemistry: application to a total synthesis of the alkaloid (±)-aspidospermidine

Abstract

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Exploiting the palladium[0]-catalysed Ullmann cross-coupling reaction in natural products chemistry: application to a total synthesis of the alkaloid (±)-aspidospermidine

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