Issue 23, 2005
From the journal:

Dalton Transactions

Construction of an interpenetrated 3-D network by [2 + 2] cycloaddition of Zn(ClO4)2 and 1,2-trans-(4-pyridyl)ethene: counter anion effects†

Jun Yong Lee,a   Sung Jin Hong,a   Cheal Kim*a  and  Youngmee Kim*b  

* Corresponding authors

a Department of Fine Chemistry, Seoul National University of Technology, Seoul, Korea
E-mail: chealkim@snut.ac.kr
Fax: +82-2-973-9149
Tel: +82-2-970-6693

b Division of Nano Sciences, Ewha Womans University, Seoul, Korea
E-mail: ymeekim@ewha.ac.kr
Fax: +82-2-3277-2384
Tel: +82-2-3277-3589

Abstract

The reaction of Zn(ClO4)2 with 1,2-trans-(4-pyridyl)ethene (bpe) results in an interpenetrated network containing both the starting bpe ligand and the newly generated 1,2,3,4-tetrakis(4-pyridyl)cyclobutane (4pycb) (formed by [2 + 2] cyclization of the starting ligand), while the reactions of Zn(NO3)2 and ZnSO4 with bpe result in a dinuclear complex and a two-dimensional sheet, respectively.

Graphical abstract: Construction of an interpenetrated 3-D network by [2 + 2] cycloaddition of Zn(ClO4)2 and 1,2-trans-(4-pyridyl)ethene: counter anion effects

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Article information

DOI
https://doi.org/10.1039/B511520E
Article type
Communication
Submitted
12 Aug 2005
Accepted
20 Sep 2005
First published
30 Sep 2005

Dalton Trans., 2005, 3716-3718

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Construction of an interpenetrated 3-D network by [2 + 2] cycloaddition of Zn(ClO4)2 and 1,2-trans-(4-pyridyl)ethene: counter anion effects

J. Yong Lee, S. Jin Hong, C. Kim and Y. Kim, Dalton Trans., 2005, 3716 DOI: 10.1039/B511520E

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