Issue 3, 2005
From the journal:

Dalton Transactions

Lanthanide mono(borohydride) complexes of diamide-diamine donor ligands: novel single site catalysts for the polymerisation of methyl methacrylate†

Fanny Bonnet,a   Anna C. Hillier,a   Anna Collins,a   Stuart R. Dubberleya  and  Philip Mountford*a  

* Corresponding authors

a Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, UK
E-mail: philip.mountford@chem.ox.ac.uk

Abstract

Samarium chloride and borohydride complexes of the diamide-diamine ligands (2-C5H4N)CH2N(CH2CH2NR)2 (R = SiMe3 or mesityl) are described; the borohydride compounds are the first polydentate amide-supported single component lanthanide catalysts for the controlled polymerisation of polar monomers, and also represent the first lanthanide borohydride complex for the polymerisation of methyl methacrylate.

Graphical abstract: Lanthanide mono(borohydride) complexes of diamide-diamine donor ligands: novel single site catalysts for the polymerisation of methyl methacrylate

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Article information

DOI
https://doi.org/10.1039/B417279P
Article type
Communication
Submitted
11 Nov 2004
Accepted
16 Dec 2004
First published
10 Jan 2005

Dalton Trans., 2005, 421-423

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Lanthanide mono(borohydride) complexes of diamide-diamine donor ligands: novel single site catalysts for the polymerisation of methyl methacrylate

F. Bonnet, A. C. Hillier, A. Collins, S. R. Dubberley and P. Mountford, Dalton Trans., 2005, 421 DOI: 10.1039/B417279P

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