Issue 3, 2005

Lanthanide mono(borohydride) complexes of diamide-diamine donor ligands: novel single site catalysts for the polymerisation of methyl methacrylate

Abstract

Samarium chloride and borohydride complexes of the diamide-diamine ligands (2-C5H4N)CH2N(CH2CH2NR)2 (R = SiMe3 or mesityl) are described; the borohydride compounds are the first polydentate amide-supported single component lanthanide catalysts for the controlled polymerisation of polar monomers, and also represent the first lanthanide borohydride complex for the polymerisation of methyl methacrylate.

Graphical abstract: Lanthanide mono(borohydride) complexes of diamide-diamine donor ligands: novel single site catalysts for the polymerisation of methyl methacrylate

Supplementary files

Article information

Article type
Communication
Submitted
11 Nov 2004
Accepted
16 Dec 2004
First published
10 Jan 2005

Dalton Trans., 2005, 421-423

Lanthanide mono(borohydride) complexes of diamide-diamine donor ligands: novel single site catalysts for the polymerisation of methyl methacrylate

F. Bonnet, A. C. Hillier, A. Collins, S. R. Dubberley and P. Mountford, Dalton Trans., 2005, 421 DOI: 10.1039/B417279P

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