Unexpected ligand substitutions in the cluster core {Re6Se8}: synthesis and structure of the novel cluster compound Cs11(H3O)[Re6Se4O4Cl6]3·4H2O

S. S. Yarovoi; Y. V. Mironov; S. F. Solodovnikov; D. Y. Naumov; N. K. Moroz; S. G. Kozlova; A. Simon; V. E. Fedorov

doi:10.1039/B412850H

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Unexpected ligand substitutions in the cluster core {Re₆Se₈}: synthesis and structure of the novel cluster compound Cs₁₁(H₃O)[Re₆Se₄O₄Cl₆]₃·4H₂O†

S. S. Yarovoi,^a Y. V. Mironov,^a S. F. Solodovnikov,^a D. Y. Naumov,^a N. K. Moroz,^a S. G. Kozlova,^ab A. Simon^c and V. E. Fedorov*^a

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* Corresponding authors

^a Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, 3, Lavrentiev Av., 630090 Novosibirsk, Russia
E-mail: fed@che.nsk.su
Fax: +7(3832)344489
Tel: +7(3832)342531

^b Boreskov Institute of Catalysis, Russian Academy of Sciences, 5, Lavrentiev Av., 630090 Novosibirsk, Russia

^c Max-Planck-Institut für Festkörperforschung, Heisenbergstraße 1, Stuttgart, Germany
E-mail: A.Simon@fkf.mpg.de

Abstract

The compound Cs₁₁(H₃O)[Re₆Se₄O₄Cl₆]₃·4H₂O containing a novel cluster core {Re₆Se₄O₄} with ordered ligands, where the 4 positions of one face of a Se₄O₄ cube are occupied exclusively by Se atoms and 4 O atoms lie in the opposite face was synthesized via the interaction of solid Re₆Se₈Br₂ with molten KOH.

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Article information

DOI: https://doi.org/10.1039/B412850H
Article type: Communication
Submitted: 20 Aug 2004
Accepted: 12 Oct 2004
First published: 21 Dec 2004

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Chem. Commun., 2005, 719-721

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Unexpected ligand substitutions in the cluster core {Re₆Se₈}: synthesis and structure of the novel cluster compound Cs₁₁(H₃O)[Re₆Se₄O₄Cl₆]₃·4H₂O

S. S. Yarovoi, Y. V. Mironov, S. F. Solodovnikov, D. Y. Naumov, N. K. Moroz, S. G. Kozlova, A. Simon and V. E. Fedorov, Chem. Commun., 2005, 719 DOI: 10.1039/B412850H

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