Issue 2, 2004
From the journal:

New Journal of Chemistry

Self-assembly route from a bis-aminal derivative to a new cyclam based macropentacycle†

Raphaël Tripier,a   Stéphanie Develay,a   Michel Le Baccon,a   Françoise Chuburu,a   François Michauda  and  Henri Handel*a  

* Corresponding authors

a Laboratoire de Chimie, Electrochimie Moléculaire et Analytique (CNRS UMR 6521), Université de Bretagne Occidentale, B. P. 809, 6 avenue Le Gorgeu, Brest cedex, France
E-mail: henri.handel@univ-brest.fr
Fax: +33 (0)2 98 01 65 94

Abstract

A new powerful two-step synthesis of a cyclam-based macropentacycle ligand is reported. In this procedure, the starting material is the bis-aminal derived from the condensation of cyclam with glyoxal. The tetrameric polyammonium intermediate issued from the self-assembly process and the free ligand were fully characterized by conventional methods and a tetranuclear Cu(II) complex was prepared.

Graphical abstract: Self-assembly route from a bis-aminal derivative to a new cyclam based macropentacycle

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Article information

DOI
https://doi.org/10.1039/B310074J
Article type
Letter
Submitted
20 Aug 2003
Accepted
30 Oct 2003
First published
12 Dec 2003

New J. Chem., 2004,28, 173-176

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Self-assembly route from a bis-aminal derivative to a new cyclam based macropentacycle

R. Tripier, S. Develay, M. Le Baccon, F. Chuburu, F. Michaud and H. Handel, New J. Chem., 2004, 28, 173 DOI: 10.1039/B310074J

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