Issue 6, 2004
From the journal:

Mendeleev Communications

Efficient resolution of the cis-[Ru(phen)2(MeCN)2]2+ complex (phen = 1,10-phenanthroline) using Δ-[tris(tetrachlorobenzenediolato)-phosphate(v)] as a chiral counter-ion

Michel Gruselle,*a   René Thouvenot,a   Régis Caspar,a   Kamal Boubekeur,a   Hani Amouri,a   Mikhail Ivanovb  and  Kaia Tõnsuaaduc  

* Corresponding authors

a Laboratoire de Chimie Inorganique et Matériaux Moléculaires, CNRS, Université Pierre et Marie Curie, Paris, France, 4 place jussieu, case 42, cedex 05, Paris, France
E-mail: gruselle@ccr.jussieu.fr

b Department of Chemistry, Russian State Pedagogical University, St. Petersburg, Russian Federation, Moika, 48, St. Petersburg, Russian Federation

c Institute of Chemical Engineering, Tallinn Technical University, Tallinn, Estonia, Ehitajate tee 5, Tallinn, Estonia

Abstract

The synthesis of cis-[Ru(phen)2(MeCN)2][(Δ)-tris(tetrachlorobenzenediolato)phosphate(v)]2 abbreviated as [1]-[Δ-TRISPHAT]2 and the separation of a mixture of the diastereomeric ion pairs by column chromatography are considered. The X-ray structure of [Δ-1][Δ-TRISPHAT]2 is briefly described, as well as the CD curves of [Δ-1][Δ-TRISPHAT]2 and [Λ-1][Δ-TRISPHAT]2 fractions.

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Article information

DOI
https://doi.org/10.1070/MC2004v014n06ABEH002034
Article type
Communication
Submitted
14 Sep 2004

Mendeleev Commun., 2004,14, 282-283

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Efficient resolution of the cis-[Ru(phen)2(MeCN)2]2+ complex (phen = 1,10-phenanthroline) using Δ-[tris(tetrachlorobenzenediolato)-phosphate(v)] as a chiral counter-ion

M. Gruselle, R. Thouvenot, R. Caspar, K. Boubekeur, H. Amouri, M. Ivanov and K. Tõnsuaadu, Mendeleev Commun., 2004, 14, 282 DOI: 10.1070/MC2004v014n06ABEH002034

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