The X-ray diffraction studies and B3LYP/6-311G* calculations of the complexes of 1-boraadamantane and 4-bromo-1-boraadamantane with THF have revealed that the introduction of a halogen atom results in a shortening of the B–O bond due to intramolecular polarization.
Intramolecular polarization of the dative B–O bond in the donor–acceptor complexes of 1-boraadamantanes with tetrahydrofuran
K. A. Lyssenko, V. A. Ponomarev, M. E. Gurskii, Y. N. Bubnov and M. Yu. Antipin, Mendeleev Commun., 2004, 14, 189 DOI: 10.1070/MC2004v014n05ABEH001920
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