The large amount of data on enzyme structures obtained to date allow us to discuss general regularities in the formation of catalytic centres of enzymes. Approaches based on a comparison of structures in large data arrays made it possible to reveal a number of non-obvious regularities and to elicit principles of the design of catalytic centres.
Catalytic centres of enzymes: structural paradoxes, the phenomenon of structural unity and new reactions
S. D. Varfolomeev, Mendeleev Commun., 2004, 14, 185 DOI: 10.1070/MC2004v014n05ABEH002020
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