The reactions of the nitroso chlorides of methylcyclohexene, limonene, 3-carene, and α-pinene with an excess of diethyl malonate in the presence of anhydrous K2CO3 at room temperature resulted in the C-alkylation and formation of α-substituted oximes with a diethyl malonate moiety in 20–90% yields.
C-Alkylation of nitroso chlorides with diethyl malonate: the X-ray structure of diethyl (±)-(1R*,2S*,5R*)-2-{3(E)-hydroxyimino-2,6,6-trimethylbicyclo[3.1.1]hept-2-yl}malonate
S. N. Bizjaev, T. V. Rybalova, Y. V. Gatilov and A. V. Tkachev, Mendeleev Commun., 2004, 14, 18 DOI: 10.1070/MC2004v014n01ABEH001799
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...