Issue 24, 2004
From the journal:

Dalton Transactions

Nucleophilic substitution on a Ru-coordinated Cp ring by a carborane anion

Marino Basato,*a   Andrea Biffis,a   Cristina Tubaro,a   Claudia Graiffb  and  Antonio Tiripicchiob  

* Corresponding authors

a Dipartimento di Scienze Chimiche, Università di Padova, via Marzolo 1, Padova, Italy
E-mail: marino.basato@unipd.it
Fax: +39 049 8275223
Tel: +39 049 8275217

b Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Università di Parma, Parco Area delle Scienze 17/A, Parma, Italy
E-mail: antonio.tiripicchio@unipr.it
Fax: +39 0521 905557
Tel: +39 0521 905418

Abstract

The Cp ring in [RuCl(Cp)(PPh3)2] undergoes an apparent nucleophilic attack by the carbanion carb− (Hcarb = 2-Me-1,2-dicarba-closo-dodecaborane), to give an H−/carb− exchange process, which is favoured by coordination of the hydride to the ruthenium centre.

Graphical abstract: Nucleophilic substitution on a Ru-coordinated Cp ring by a carborane anion

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Article information

DOI
https://doi.org/10.1039/B413803A
Article type
Communication
Submitted
08 Sep 2004
Accepted
22 Oct 2004
First published
11 Nov 2004

Dalton Trans., 2004, 4092-4093

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Nucleophilic substitution on a Ru-coordinated Cp ring by a carborane anion

M. Basato, A. Biffis, C. Tubaro, C. Graiff and A. Tiripicchio, Dalton Trans., 2004, 4092 DOI: 10.1039/B413803A

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