Issue 6, 2004
From the journal:

Chemical Communications

Mixed halo/hydroxy carborane anions: thermally stable platforms for hydronium ion isolation†

Daniel J. Stasko,*a   Kevin J. Perzynskia  and  Mark A. Wasila  

* Corresponding authors

a Dept. of Chemistry, University of Toledo, Toledo, OH 43605, USA
E-mail: daniel.stasko@utoledo.edu
Fax: +1 419-530-4033
Tel: +1 419-530-4087

Abstract

Hydroxylation of the robust, weakly coordinating hexahalo- carborane anion system, CB11H6Br6−1, produces a new class of anion with mixed halo/hydroxyl substituents, HCB11(OH)5Br6−1 which can be used to isolate a number of hydronium cation salts including an ‘ice tautomer’ composed of hydronium cation, anion hydroxyl groups and coordinated water molecules.

Graphical abstract: Mixed halo/hydroxy carborane anions: thermally stable platforms for hydronium ion isolation

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Article information

DOI
https://doi.org/10.1039/B314475E
Article type
Communication
Submitted
11 Nov 2003
Accepted
22 Dec 2003
First published
16 Feb 2004

Chem. Commun., 2004, 708-709

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Mixed halo/hydroxy carborane anions: thermally stable platforms for hydronium ion isolation

D. J. Stasko, K. J. Perzynski and M. A. Wasil, Chem. Commun., 2004, 708 DOI: 10.1039/B314475E

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