Issue 4, 2004
From the journal:

Chemical Communications

Proton transferversus redox modulation in thiourea-phenanthrenequinone molecular and polymeric complexes†

Joseph B. Carroll,a   Mark Gray,a   Graeme Cookeb  and  Vincent M. Rotello*a  

* Corresponding authors

a Department of Chemistry, The University of Massachusetts, Amherst, MA 01003, USA
E-mail: rotello@chem.umass.edu.

b Centre for Biomimetic Design and Synthesis, Chemistry, Heriot-Watt University, Riccarton, Edinburgh, UK

Abstract

Phenanthrenequinone undergoes highly efficient proton transfer processes in the presence of a thiourea-funtionalised polystyrene copolymer whereas interactions with a similar benzyl-thiourea monomer show strong redox modulation of the quinone without proton transfer.

Graphical abstract: Proton transfer versus redox modulation in thiourea-phenanthrenequinone molecular and polymeric complexes

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Article information

DOI
https://doi.org/10.1039/B312349A
Article type
Communication
Submitted
08 Oct 2003
Accepted
22 Dec 2003
First published
23 Jan 2004

Chem. Commun., 2004, 442-443

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Proton transfer versus redox modulation in thiourea-phenanthrenequinone molecular and polymeric complexes

J. B. Carroll, M. Gray, G. Cooke and V. M. Rotello, Chem. Commun., 2004, 442 DOI: 10.1039/B312349A

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