Issue 7, 2003
From the journal:

Organic & Biomolecular Chemistry

A highly selective route to β-C-glycosides via nonselective samarium iodide induced coupling reactions

Sara Palmier,a   Boris Vauzeillesa  and  Jean-Marie Beau*a  

* Corresponding authors

a Université Paris-Sud, Laboratoire de Synthèse de Biomolécules associé au CNRS, Institut de Chimie Moléculaire et des Matériaux, F-91405 Orsay Cedex, France
E-mail: jmbeau@icmo.u-psud.fr
Fax: (+33) 1 69 85 37 15

Abstract

Stereoselective preparation of β-C-glycosides has been developed from acetylated glycopyranosyl 2-pyridyl sulfones, involving a samarium-Barbier coupling procedure–oxidation–isomerization sequence.

Graphical abstract: A highly selective route to β-C-glycosides via nonselective samarium iodide induced coupling reactions

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Article information

DOI
https://doi.org/10.1039/B301805A
Article type
Communication
Submitted
14 Feb 2003
Accepted
18 Feb 2003
First published
28 Feb 2003

Org. Biomol. Chem., 2003,1, 1097-1098

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A highly selective route to β-C-glycosides via nonselective samarium iodide induced coupling reactions

S. Palmier, B. Vauzeilles and J. Beau, Org. Biomol. Chem., 2003, 1, 1097 DOI: 10.1039/B301805A

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