Issue 9, 2003
From the journal:

New Journal of Chemistry

Solvent effect on the structure and topology of metal-organic frameworks with the rigid tripodal star ligand1,3,5-tris(1-imidazolyl)benzene and lead(ii) nitrate†

Jian Fan,a   Mou-Hai Shu,b   Taka-aki Okamura,c   Yi-Zhi Li,a   Wei-Yin Sun,*a   Wen-Xia Tanga  and  Norikazu Ueyamac  

* Corresponding authors

a Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, China
E-mail: sunwy@nju.edu.cn

b School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai, China

c Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka, Japan

Abstract

Reaction of 1,3,5-tris(1-imidazolyl)benzene with Pb(NO3)2 in DMF affords a novel metal-organic framework with 4.82 topology in which the DMF molecules are attached to the channel walls, while in the reaction carried out in methanol, a one-dimensional coordination polymer was obtained.

Graphical abstract: Solvent effect on the structure and topology of metal-organic frameworks with the rigid tripodal star ligand 1,3,5-tris(1-imidazolyl)benzene and lead(ii) nitrate

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Article information

DOI
https://doi.org/10.1039/B306876P
Article type
Letter
Submitted
12 May 2003
Accepted
27 Jun 2003
First published
24 Jul 2003

New J. Chem., 2003,27, 1307-1309

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Solvent effect on the structure and topology of metal-organic frameworks with the rigid tripodal star ligand 1,3,5-tris(1-imidazolyl)benzene and lead(II) nitrate

J. Fan, M. Shu, T. Okamura, Y. Li, W. Sun, W. Tang and N. Ueyama, New J. Chem., 2003, 27, 1307 DOI: 10.1039/B306876P

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