Issue 4, 2003
From the journal:

Mendeleev Communications

New polysulfur–nitrogen heterocycles as precursors of thiazyl radicals

Konstantin V. Shuvaev,a   Victor A. Bagryansky,b   Nina P. Gritsan,b   Alexander Yu. Makarov,c   Yuri N. Molinb  and  Andrey V. Zibarevc  

a Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation, ul. Pirogova, 2, Novosibirsk, Russian Federation

b Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation, Institutskaya ul.,3, Novosibirsk, Russian Federation

c N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation, Prospekt Akademika Lavrent'eva, 9, Novosibirsk, Russian Federation

Abstract

Both thermolysis and photolysis of 1,2,4λ4δ2,3,5- and 1,3λ4δ2,5,2,4-benzotrithiadiazepines in hydrocarbon solvents yielded stable 1,2,3- and 1,3,2-benzodithiazolyls, which can be considered as a particular case of a previously unmentioned trend of neutral polysulfur–nitrogen heterocycles to form thiazyl π-radicals.

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Article information

DOI
https://doi.org/10.1070/MC2003v013n04ABEH001741
Article type
Communication
Submitted
21 Mar 2003

Mendeleev Commun., 2003,13, 178-179

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New polysulfur–nitrogen heterocycles as precursors of thiazyl radicals

K. V. Shuvaev, V. A. Bagryansky, N. P. Gritsan, A. Yu. Makarov, Y. N. Molin and A. V. Zibarev, Mendeleev Commun., 2003, 13, 178 DOI: 10.1070/MC2003v013n04ABEH001741

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