Stability of low-spin ferric hydroperoxo and alkylperoxo complexes with tris(2-pyridylmethyl)amine
Abstract
Quantitative data on the stability and reactivity of the peroxidic intermediates [FeIII(TPA)(OOH)L](ClO4)2 and [FeIII(TPA)(OOBut)L](ClO4)2 [TPA = tris(2-pyridylmethyl)amine; L = MeCN, H2O, MeOH and Py] were obtained for the first time.