Issue 4, 2003

Stability of low-spin ferric hydroperoxo and alkylperoxo complexes with tris(2-pyridylmethyl)amine

Abstract

Quantitative data on the stability and reactivity of the peroxidic intermediates [FeIII(TPA)(OOH)L](ClO4)2 and [FeIII(TPA)(OOBut)L](ClO4)2 [TPA = tris(2-pyridylmethyl)amine; L = MeCN, H2O, MeOH and Py] were obtained for the first time.

Article information

Article type
Communication
Submitted
17 Feb 2003

Mendeleev Commun., 2003,13, 175-177

Stability of low-spin ferric hydroperoxo and alkylperoxo complexes with tris(2-pyridylmethyl)amine

M. V. Lobanova, K. P. Bryliakov, E. A. Duban and E. P. Talsi, Mendeleev Commun., 2003, 13, 175 DOI: 10.1070/MC2003v013n04ABEH001727

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