Issue 4, 2003
From the journal:

Dalton Transactions

Monohapto-allyl Pd(ii) complexes with bidentate hybrid P,N ligands†

Pierre Braunstein,a   Jing Zhanga  and  Richard Welterb  

a Laboratoire de Chimie de Coordination, UMR CNRS 7513, Université Louis Pasteur, 4 rue Blaise Pascal, F-67070 Strasbourg Cédex, France
E-mail: braunst@chimie.u-strasbg.fr

b Laboratoire DECMET, UMR CNRS 7513, Université Louis Pasteur, 4 rue Blaise Pascal, F-67070 Strasbourg Cédex, France

Abstract

Using a new oxazoline-phosphonite P,N ligand, we establish that in contrast with commonly held belief, bidentate ligands can lead to unusually stable η1-allyl complexes of Pd(II); CO insertion into their Pd–C σ-bond affords the corresponding 3-butenoyl complexes under mild conditions.

Graphical abstract: Monohapto-allyl Pd(ii) complexes with bidentate hybrid P,N ligands

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Article information

DOI
https://doi.org/10.1039/B212393M
Article type
Communication
Submitted
13 Dec 2002
Accepted
09 Jan 2003
First published
21 Jan 2003

Dalton Trans., 2003, 507-509

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Monohapto-allyl Pd(II) complexes with bidentate hybrid P,N ligands

P. Braunstein, J. Zhang and R. Welter, Dalton Trans., 2003, 507 DOI: 10.1039/B212393M

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