Issue 13, 2003
From the journal:

CrystEngComm

An organoplatinum molecular hexagon that crystallizes in a hexagonal array

Mehdi Rashidi,a   Michael C. Jenningsa  and  Richard J. Puddephatt*a  

* Corresponding authors

a Department of Chemistry, University of Western Ontario, London, Canada

Abstract

The complex [PtMe(dppa)(PPh2O)], dppa = Ph2PNHPPh2, which contains chelating dppa and P-bonded diphenylphosphinito ligands, is formed as an insoluble complex on hydrolysis of [PtMe2(dppa)] or by reaction of [PtMe2(dppa)] with Ph2PH([double bond, length as m-dash]O); the complex undergoes self-assembly by intermolecular hydrogen bonding NH⋯OP to form molecular hexagons, that further pack with a hexagonal motif in the crystal lattice.

Graphical abstract: An organoplatinum molecular hexagon that crystallizes in a hexagonal array

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Article information

DOI
https://doi.org/10.1039/B212734B
Article type
Communication
Submitted
03 Jan 2003
Accepted
29 Jan 2003
First published
05 Feb 2003

CrystEngComm, 2003,5, 65-66

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An organoplatinum molecular hexagon that crystallizes in a hexagonal array

M. Rashidi, M. C. Jennings and R. J. Puddephatt, CrystEngComm, 2003, 5, 65 DOI: 10.1039/B212734B

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