The relative and absolute stereochemistry of amphidinoketide I has been determined by the total synthesis of all the diastereoisomers. Molecular modelling suggests that the natural product is not the thermodynamically preferred diastereoisomer.
L. M. Walsh and J. M. Goodman, Chem. Commun., 2003, 2616 DOI: 10.1039/B309104J
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