Issue 21, 2003
From the journal:

Chemical Communications

Single-molecule magnets: control by a single solvent molecule of Jahn–Teller isomerism in [Mn12O12(O2CCH2But)16(H2O)4]

Mònica Soler,a   Wolfgang Wernsdorfer,b   Ziming Sun,d   John C. Huffman,c   David N. Hendricksond  and  George Christou*a  

* Corresponding authors

a Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA
E-mail: christou@chem.ufl.edu
Tel: +1 352-392-8314

b Laboratoire Louis Néel-CNRS, BP 166, 38042 Grenoble, Cedex 9, France

c Department of Chemistry and Structure Center, Indiana University, Bloomington, Indiana, 47401-4001, USA

d Department of Chemistry, University of California at San Diego, La Jolla, California, 92093-0358, USA

Abstract

Faster- and slower-relaxing versions of the title Mn12 compound have been obtained in pure forms that crystallize in the same space group and differ only in the identity of one lattice solvent molecule; solvent loss causes isomerization from the faster- to the slower-relaxing form.

Graphical abstract: Single-molecule magnets: control by a single solvent molecule of Jahn–Teller isomerism in [Mn12O12(O2CCH2But)16(H2O)4]

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Article information

DOI
https://doi.org/10.1039/B306246E
Article type
Communication
Submitted
02 Jun 2003
Accepted
05 Sep 2003
First published
25 Sep 2003

Chem. Commun., 2003, 2672-2673

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Single-molecule magnets: control by a single solvent molecule of Jahn–Teller isomerism in [Mn12O12(O2CCH2But)16(H2O)4]

M. Soler, W. Wernsdorfer, Z. Sun, J. C. Huffman, D. N. Hendrickson and G. Christou, Chem. Commun., 2003, 2672 DOI: 10.1039/B306246E

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