Issue 20, 2003
From the journal:

Chemical Communications

3D porous and 3D interpenetrating triple framework structures constructed by aurophilicity-coordination interplay in {Mn[Au(CN)2]2(H2O)2}n and {KFe[Au(CN)2]3}n

Wen Dong,a   Li-Na Zhu,a   Ya-Qiu Sun,a   Mao Liang,a   Zhan-Quan Liu,a   Dai-Zheng Liao,*a   Zong-Hui Jiang,ab   Shi-Ping Yana  and  Peng Chenga  

* Corresponding authors

a Department of Chemistry, Nankai University, Tianjin 300071, P. R. China
E-mail: coord@nankai.edu.cn
Tel: +86 022-23509957

b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China

Abstract

Two cyano-bridged heterobimetallic coordination polymers {Mn[Au(CN)2]2(H2O)2}n (1) and {KFe[Au(CN)2]3}n (2), have been synthesized from [Au(CN)2]− building blocks and structurally characterized. In both complexes aurophilicity play an important role in determining the 3D open microporous framework and the interpenetrating triple framework for 1 and 2, respectively. Both aqueous solutions of 1 and 2 display interesting luminescent properties.

Graphical abstract: 3D porous and 3D interpenetrating triple framework structures constructed by aurophilicity-coordination interplay in {Mn[Au(CN)2]2(H2O)2}n and {KFe[Au(CN)2]3}n

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B306026H
Article type
Communication
Submitted
28 May 2003
Accepted
29 Aug 2003
First published
11 Sep 2003

Chem. Commun., 2003, 2544-2545

Permissions

Request permissions

3D porous and 3D interpenetrating triple framework structures constructed by aurophilicity-coordination interplay in {Mn[Au(CN)2]2(H2O)2}n and {KFe[Au(CN)2]3}n

W. Dong, L. Zhu, Y. Sun, M. Liang, Z. Liu, D. Liao, Z. Jiang, S. Yan and P. Cheng, Chem. Commun., 2003, 2544 DOI: 10.1039/B306026H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements