Issue 14, 2003
From the journal:

Chemical Communications

Stereospecific isomerisation of P-heterocycles triggered by coordination: synthesis of the first P,N-chelates featuring a 2-phospholene moiety

François Leca,a   Mathieu Sauthier,a   Boris le Guennic,b   Christophe Lescop,a   Loic Toupet,c   Jean-François Haletb  and  Régis Réau*a  

* Corresponding authors

a UMR 6509 CNRS-Université de Rennes 1, Institut de Chimie, Campus de Beaulieu, 35042 Rennes Cedex, France
E-mail: regis.reau@univ-rennes1.fr
Fax: (+33)2-23236939
Tel: (+33)2-23235784

b UMR 6511 CNRS-Université de Rennes 1, Institut de Chimie, Campus de Beaulieu, 35042 Rennes Cedex, France

c UMR 6626 CNRS-Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex, France

Abstract

Coordination of 2-(2-pyridyl)phospholes on Pd(II) centres results in a ring strain sufficient to induce a stereospecific [1,3]-H migration affording the corresponding phospholene ligands.

Graphical abstract: Stereospecific isomerisation of P-heterocycles triggered by coordination: synthesis of the first P,N-chelates featuring a 2-phospholene moiety

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Article information

DOI
https://doi.org/10.1039/B304308H
Article type
Communication
Submitted
22 Apr 2003
Accepted
30 May 2003
First published
16 Jun 2003

Chem. Commun., 2003, 1774-1775

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Stereospecific isomerisation of P-heterocycles triggered by coordination: synthesis of the first P,N-chelates featuring a 2-phospholene moiety

F. Leca, M. Sauthier, B. L. Guennic, C. Lescop, L. Toupet, J. Halet and R. Réau, Chem. Commun., 2003, 1774 DOI: 10.1039/B304308H

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