Issue 13, 2003
From the journal:

Chemical Communications

Noncatalytic Heck coupling reaction using supercritical water

Rong Zhang,a   Fengyu Zhao,ab   Masahiro Satoa  and  Yutaka Ikushima*ab  

* Corresponding authors

a Supercritical Fluid Research Center, National Institute of Advanced Industrial Science and Technology, 4-2-1 Nigatake, Miyagino-ku, Sendai 983-8551, Japan
E-mail: y-ikushima@aist.go.jp
Fax: +81-22-237-5224
Tel: +81-22-237-5211

b CREST, Japan Science and Technology Corporation (JST), Honcho, Kawaguchi 332-0012, Japan

Abstract

Heck coupling of iodobenzene with styrene can be promoted in supercritical water without using catalyst, and the conversion reaches over 70% within 10 min in the presence of base, such as KOAc, in which case the yield of stilbene is 55.6% (both trans- and cis-stilbene).

Graphical abstract: Noncatalytic Heck coupling reaction using supercritical water

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Article information

DOI
https://doi.org/10.1039/B302683C
Article type
Communication
Submitted
10 Mar 2003
Accepted
24 Apr 2003
First published
02 Jun 2003

Chem. Commun., 2003, 1548-1549

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Noncatalytic Heck coupling reaction using supercritical water

R. Zhang, F. Zhao, M. Sato and Y. Ikushima, Chem. Commun., 2003, 1548 DOI: 10.1039/B302683C

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