Issue 5, 2003
From the journal:

Chemical Communications

An N-lithio-indole from the reaction of LiCH(TMS)2 and PhNC

Manuel A. Fernandes,a   Michael F. Lappert,b   Marcus Layh*a  and  Bernard Omondia  

* Corresponding authors

a Molecular Science Institute, School of Chemistry, University of the Witwatersrand, Private Bag 3, Wits, Johannesburg, South Africa
E-mail: marcus@aurum.chem.wits.ac.za
Fax: +27 11 7176749
Tel: +27 11 7176744

b The Chemistry Laboratory, University of Sussex, Brighton, UK
E-mail: M.F.Lappert@sussex.ac.uk
Tel: +44 1273 678316

Abstract

The reaction of LiCH(TMS)2 with phenyl isocyanide PhNC has unexpectedly led to the N-lithio-indole derivative 1, that has been fully characterised including its X-ray crystal structure determination.

Graphical abstract: An N-lithio-indole from the reaction of LiCH(TMS)2 and PhNC

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Article information

DOI
https://doi.org/10.1039/B212103D
Article type
Communication
Submitted
05 Dec 2002
Accepted
03 Feb 2003
First published
11 Feb 2003

Chem. Commun., 2003, 656-657

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An N-lithio-indole from the reaction of LiCH(TMS)2 and PhNC

M. A. Fernandes, M. F. Lappert, M. Layh and B. Omondi, Chem. Commun., 2003, 656 DOI: 10.1039/B212103D

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