Issue 10, 2002

Aminolysis of cyclic thioxocarbonate of (R,R)-di-tert-butyl tartrate: efficient access to thio- and thiolcarbamates

Abstract

Aminolysis of cyclic thioxocarbonates derived from (R,R)-dialkyl tartrates with secondary amines is described to afford efficiently thio- and thiolcarbamates in a fast and high yielding reaction. Their stereochemistry and mechanism of formation are discussed.

Graphical abstract: Aminolysis of cyclic thioxocarbonate of (R,R)-di-tert-butyl tartrate: efficient access to thio- and thiolcarbamates

Article information

Article type
Paper
Submitted
18 Feb 2002
Accepted
05 Apr 2002
First published
25 Apr 2002

J. Chem. Soc., Perkin Trans. 1, 2002, 1253-1259

Aminolysis of cyclic thioxocarbonate of (R,R)-di-tert-butyl tartrate: efficient access to thio- and thiolcarbamates

L. Faissat, C. Chavis, J. Montéro and M. Lucas, J. Chem. Soc., Perkin Trans. 1, 2002, 1253 DOI: 10.1039/B201691E

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